Handbook of RAFT Polymerization

Reversible Addition Fragmentation Chain Transfer (RAFT) technology is one of the most important new developments in polymer chemistry. The most significant benefit of RAFT polymerization is that it allows the preparation of new polymeric architectures with defined properties.
Spanning the entire field from fundamentals to applications in material science, this one–stop source is the first comprehensive reference on this hot topic for polymer, physical and surface chemists, materials scientists, chemical engineers, and those chemists working in industry.
Edited by a rising star within the community, this Handbook assembles the latest knowledge about RAFT, ranging from its mechanistic underpinnings to practical applications, providing high value for researchers and research managers seeking up–to–date information about the RAFT process, its scope and limitations.
From the contents:
∗ Introduction: Living Free Radical Polymerization and the RAFT Process
∗ Fundamental Structure–Reactivity Correlations Governing the RAFT Process
∗ Mechanism and Kinetics
∗ The RAFT Process as a Kinetic Tool
∗ Theory and Practice in Technical Applications
∗ RAFT Polymerization in Bulk and Organic Solvents, as well as Homogeneous Aqueous Systems
∗ Emulsion and Mini–Emulsion Polymerization
∗ Complex Architecture Design
∗ Macromolecular Design via the Interchange of Xanthates
∗ Surface Modification
∗ Stability and Physical Properties of RAFT Polymers
∗ Novel Materials: From Drug Delivery to Opto–Electronics


Spis treści:
List of Contributors.
1. Introduction (Christopher Barner–Kowollik)
2. Quantum–Chemical Studies of RAFT Polymerization: Methodology, Structure–reactivity Correlations and Kinetic Implications (Michelle L. Coote, Elizabeth H. Krenske, Ekaterina I. Izgorodina)
3. The Mech anism and Kinetics of the RAFT Process: Overview, Rates, Stabilities, Side reactions, Product Spectrum and Outstanding Challenges (Braeme Moad, Christopher Barner–Kowollik)
4. The RAFT Process as a Kinetic Tool: Accessing Fundamental Parameters of Free Radical Polymerization (Thomas Junkers, Tara M. Lovestaead, Christopher Barner–Kowollik)
5. The Radical Chemistry of thiocarbonylthio Compounds: An Overview (Samir Z. Zard)
6. RAFT Polymerization in Bulk Monomer or in (Organic) Solution (Ezio Rizzardo, Graeme Moad, San H. Thank)
7. RAFT Polymerization in Homogeneous Aqueous Media: Initiation Systems, RAFT Agent Stability, Monomers and Polymer Structures (Andrew B. Low, Charles L. McCormic)
8. RAFT–Mediated Polymerization in Heterogeneous Systems (Carl N. Urbani, Michael J. Monteiro)
9. Complex Architecture Design via the RAFT Process: Scope, Strengths and Limitations (Martina H. Stenzel)
10. Macromolecular Design by Interchange of Xanthates: Background, Design, Scope and Applications (Daniel Taton, Mathias Destarac, Samir Z. Zard)
11. Surface and Particle Modification via the RAFT Process: Approach and Properties (Yu Li, Linda S. Schadler, Brian C. Benicewicz)
12. Polymers with Well–Defined End Groups via RAFT–Synthesis, Applications and Postmodification (Leonie Barner, Sebastein Perrier)
13. Toward New Materials Prepared via the Raft Process: From Drug Delivery to Optoelectronics? (Arnaud Fovier, Bertrand de Lambert, Marie–Therese Charreyre)
Subject Index.

Nota biograficzna:
Professor Barner–Kowollik completed his PhD at the University of Goettingen, before joining the Centre for Advanced Macromolecular Design (CAMD) in Sydney, Australia. He has published over 110 peer reviewed research papers, over 80 conference papers and 5 book chapters. He has received several awards for his work, including the Rennie Medal of the Royal Australian Chemical Institute and the Edgeworth Davi d Medal of the Royal Society of New South Wales.

Okładka tylna:
Reversible Addition Fragmentation Chain Transfer (RAFT) technology is one of the most important new developments in polymer chemistry. The most significant benefit of RAFT polymerization is that it allows the preparation of new polymeric architectures with defined properties.
Spanning the entire field from fundamentals to applications in material science, this one–stop source is the first comprehensive reference on this hot topic for polymer, physical and surface chemists, materials scientists, chemical engineers, and those chemists working in industry.
Edited by a rising star within the community, this Handbook assembles the latest knowledge about RAFT, ranging from its mechanistic underpinnings to practical applications, providing high value for researchers and research managers seeking up–to–date information about the RAFT process, its scope and limitations.
From the contents:
∗ Introduction: Living Free Radical Polymerization and the RAFT Process
∗ Fundamental Structure–Reactivity Correlations Governing the RAFT Process
∗ Mechanism and Kinetics
∗ The RAFT Process as a Kinetic Tool
∗ Theory and Practice in Technical Applications
∗ RAFT Polymerization in Bulk and Organic Solvents, as well as Homogeneous Aqueous Systems
∗ Emulsion and Mini–Emulsion Polymerization
∗ Complex Architecture Design
∗ Macromolecular Design via the Interchange of Xanthates
∗ Surface Modification
∗ Stability and Physical Properties of RAFT Polymers
∗ Novel Materials: From Drug Delivery to Opto–Electronics