Modern Heterogeneous Oxidation Catalysis: Design, Reactions and Characterization

Heterogeneous oxidation catalysis is of enormous importance, since it is one of the key reactions in chemistry, especially in industrial chemistry. This technology reduces chemical waste, making reactions much more efficient. Today, more than ever, there is a real need for novel environmentally friendly "green" oxidants, such as oxygen, hydrogen peroxide and others.
Filling a gap in the literature, this long–awaited and comprehensive reference presents all important catalyst classes, including metal oxides, polyoxometalates, and zeolites. Readers will find here everything they need to know –– from structure design to characterization, and from immobilization to industrial processes.
From the contents:
∗ Concepts in Selective Oxidation of Small Alkane Molecules
∗ Active Ensemble Structures for Selective Oxidation Catalyses at Surfaces
∗ Unique Catalytic Performance of Supported Gold Nanoparticles in Oxidation
∗ Metal–Substituted Zeolites as Heterogeneous Oxidation Catalysts
∗ Design of Well–Defined Active Sites on Crystalline Materials for Liquid–Phase Oxidations
∗ Liquid–Phase Oxidations with Hydrogen Peroxide and Molecular Oxygen Catalyzed by Polyoxometalate–Based Compounds
∗ Nitrous Oxide as an Oxygen Donor in Oxidation Chemistry and Catalysis
∗ Direct Synthesis of Hydrogen Peroxide: Recent Adcances
∗ Recent Achievements and Challenges for a Greener Chemical Industry
A true must–have for anyone working in this key technology, whether in academia or industry.


Spis treści:
Preface
CONCEPTS IN SELECTIVE OXIDATION OF SMALL ALKENE MOLECULES
The Research Field
Substrate Activation
Active Oxygen Species
Catalyst Material Science
ACTIVE ENSEMBLE STRUCTURES FOR SELECTIVE OXIDATION CATALYSES AT SURFACES
Chiral Self–Dimerization of Vanadium Schiff–Base Complexes on SiO2 and Their Catalytic Performances for Asymmetric Oxidative Coupling of 2–Naphtol
Low–Temperature Preferential Oxidation of CO in Excess H2 on Cu–Clusters Dispersed on CeO2
Direct Phenol Synthesis from Benzene and Molecular Oxygen on a Novel N–Interstitial Re10–Cluster/HZSM–5 Catalyst
UNIQUE CATALYTIC PERFORMANCE OF SUPPORTED GOLD NANOPARTICLES IN OXIDATION
Low Temperature CO Oxidation
Complete Oxidation of Volatile Organic Compounds
Gas Phase Selective Oxidation of Aliphatic Compounds
Liquid Phase Selective Oxidation of Organic Compounds
METAL–SUBSTITUTED ZEOLITES AS HETEROGENEOUS OXIDATION CATALYSTS
Two Ways to Introduce Hetero Metals into Zeolites
Titanium–Containing Zeolites
Other Metal Containing Zeolites
DESIGN OF WELL–DEFINED ACTIVES SITES ON CRYSTALLINE MATERIALS FOR LIQUID–PHASE OXIDATIONS
Oxidation of Alcohols
Epoxidation of Olefins
cis–Dihydroxylation
Baeyer–Villiger Oxidation
C–H Activation Using Molecular Oxygen
LIQUID–PHASE OXIDATIONS WITH HYDROGEN PEROXIDE AND MOLECULAR OXYGEN CATALYZED BY POLYOXOMETALATE–BASED COMPOUNDS
Molecular Design of Polyoxometalates for H2O2–and O2–Based Oxidations
Heterogenization of Polyoxometalates
NITROUS OXIDE AS AN OXYGEN DONOR IN OXIDATION CHEMISTRY AND CATALYSIS
Molecular Structure and Physical Properties of Nitrous Oxide
Catalytic Oxidation by Nitrous Oxide in the Gas Phase
Catalytic Oxidation by N2O in the Liquid Phase
Non–Catalytic Oxidations by N2O
Economic Aspects of N2O Oxidant
DIRECT SYNTHESIS OF HYDROGEN PEROXIDE: RECENT ADVANCES
Direct Synthesis of H2O2 in an Industrial Perspective
Fundamental Studies
RECENT ACHIEVEMENTS AND CHALLENGES FOR A GREENER CHEMICAL INDUSTRY
Old and New Challenges for Oxidation Catalysis in Industry
Recent Succesful Examples of Alkanes Oxidation
New Oxidation Technologies: The Oxidative Desulphurisation (ODS) of Gasoil
Process Intensification in Catalytic Oxidation
An Alternative Approach: The Anaerobic Oxidation with Metal Oxides in a Cycle Process (from an Oxidation Catalyst to a Reusable Stoichiometric Oxidant)
Current and Developing Processes of Bio–Platform Molecules Transformation to Chemicals by Catalytic Oxidation

Nota biograficzna:
Noritaka Mizuno received his Ph. D. in 1985 at the University of Tokyo. In 1989 he did a postdoctoral work with Professor Richard G. Finke at University of Oregon and returned to Japan as an Associate Professor at Catalysis Research Center, Hokkaido University (1990). Afterwards, he moved to the Institute of Industrial Science, the University of Tokyo, and then to the Department of Applied Chemistry of the same university, where he has been a full Professor since 2001. Professor Mizuno has authored over 200 scientific publications.

Okładka tylna:
Heterogeneous oxidation catalysis is of enormous importance, since it is one of the key reactions in chemistry, especially in industrial chemistry. This technology reduces chemical waste, making reactions much more efficient. Today, more than ever, there is a real need for novel environmentally friendly "green" oxidants, such as oxygen, hydrogen peroxide and others.
Filling a gap in the literature, this long–awaited and comprehensive reference presents all important catalyst classes, including metal oxides, polyoxometalates, and zeolites. Readers will find here everything they need to know –– from structure design to characterization, and from immobilization to industrial processes.
From the contents:
∗ Concepts in Selective Oxidation of Small Alkane Molecules
∗ Active Ensemble Structures for Selective Oxidation Catalyses at Surfaces
∗ Unique Catalytic Performance of Supported Gold Nanoparticles in Oxidation
∗ Metal–Substituted Zeolites as Hetero geneous Oxidation Catalysts
∗ Design of Well–Defined Active Sites on Crystalline Materials for Liquid–Phase Oxidations
∗ Liquid–Phase Oxidations with Hydrogen Peroxide and Molecular Oxygen Catalyzed by Polyoxometalate–Based Compounds
∗ Nitrous Oxide as an Oxygen Donor in Oxidation Chemistry and Catalysis
∗ Direct Synthesis of Hydrogen Peroxide: Recent Adcances
∗ Recent Achievements and Challenges for a Greener Chemical Industry
A true must–have for anyone working in this key technology, whether in academia or industry.