Inorganic Syntheses

New procedures and compounds for students and professionals in the field of inorganic chemistry
The Inorganic Syntheses series provides all users of inorganic substances with detailed and foolproof procedures for the preparation of important and timely compounds. In Volume 33, editor Dimitri Coucouvanis collects syntheses that present new or revised experimental procedures that are applicable to a variety of related compounds, as well as syntheses of individual compounds that are of interest or importance. Chapter topics are comprised of syntheses of selected supramolecules, useful reagents/ligands, solid state materials/clusters, and compounds of general interest, including mesityl–gold (I)complexes and zero valent binuclear nickel complexes, among many others
All the syntheses presented have been tested. Inorganic, organic, and organometallic chemists, as well as materials scientists, instructors, and graduate students will find the research, methods, and compounds contained here invaluable to their scientific pursuits.

Spis treści:
Chapter One. SYNTHESES OF SELECTEDSUPRAMOLECULES.
1. Toward Magnetic Building Blocks: Synthesis of a PlanarCo(III) cation Radical cobalt(III) Complex of the BinucleatingLigand 1,2,4,5–Tetrakis(2–hydroxy–2–methylpropanamido)benzene.
2. A Luminescent Decanuclear Ruthenium(II) Polypyridine Complex:A Convergent Approach to a Dendritic Structure Employingthe ‘‘Complexes as Metals/Complexes asLigands’’ Synthetic Strategy.
3. Dodecatungstoaluminic Acid and Its Monolacunary andMixed–Addendum Derivatives.
Supramolecular Complexes of BisBis(2,2′–bipyridine)osmium(II) and Ruthenium(II).
5. Binuclear Oxomolybdenum Metalloporphyrin Complexes.
6. Iron Sandwich Polyoxoanion Compounds.
7. Dipyrryl and Porphyrinic Precursors to Supramolecular Conjugated(Porphinato)metal Arrays: Syntheses of Dipyrrylmethaneand (5,15–diphe nylporphinato)zinc(II).
8. Synthesis of Dodecaoxohexadecacarboxylatotetraaquo–dodecamanganese[Mn12 O12 (O2 CR)16 (H2 O)4 ](R¼Me,Et,Ph,Cr) Complexes.
9. Use of Picolinehydroximate Complexes in Preparation ofUranyl and Lanthanide 15–Metallacrown–5:UO2 (NO3 )2 [15–MCCu(II)N(pic)–15] and{Eu(NO3 )2 [15–MCCu(II)N(pic)–15]}NO3.
10. Use of Salicyl– and Naphthoylhydroximate Complexes inPreparation of Manganese and Copper 12–Metallacrown–4Complexes: Mn(II)(Acetate)2 [Mn(III)(salicylhydroximate)]4 and(Tetramethylammonium)2 [Cu(II)5 (naphthoylhydroximate)4 ].
Chapter Two. USEFUL REAGENTS AND LIGANDS.
11. Homoleptic Transition Metal Acetonitrile Cations withTetrafluoroborate or Trifluoromethanesulfonate Anions.
12. Synthesis of [MII(NCMe)6 ]2þ (M¼V,Cr,Mn,Fe,Co,Ni)Salts of Tetra[3,5–bis(trifluoromethyl)phenyl]borate.
13. Transition Metal p–Toluenesulfonates.
14. Salts of Binuclear Iron(II) and Iron(III) Dianions[(Fe2 Cl6 )2and (Fe2 OCl6 )2].
15. Tetraethylammonium–Tetrathioperrhenate Et4 N(ReS4 ).
16. Large–Scale Synthesis of Methyltrioxorhenium (CH3 ReO3 ).
17. 4,5–Diaminocatechol: A Useful Building Block inSynthesis of Multimetallic Complexes.
18. A Convenient Synthesis of 1,5,9–Trithiacyclododecane(S3 C9 H18 ).