Organometallic Compounds of Low–Coordinate Si, Ge, Sn and Pb: From Phantom Species to Stable Compounds

Preface
Abbreviations
1. Heavy Analogues of Carbenium ions: Si–, Ge–, Sn– and Pb–Centered Cations
1.1 Introduction
1.2 Synthesis of RR’R’’E+ cations (E = Si–Pb)
1.3 Reactions and synthetic applications of RR’R’’E+ cations
1.4 Theoretical studies
1.5 Early studies of RR’R’’E+ cations: Free or Coordinated?
1.6 Stable RR’R’’E+ cations
1.7 Summary and outlook
References
2. Heavy Analogues of Organic Free Radicals: Si–, Ge–, Sn– and Pb–centered Radicals
2.1 Introduction
2.2 Early studies: transient species RR’R’’E•
2.3 Persistent radicals (generation and identification)
2.4 Stable radicals
2.5 Summary and outlook
References
3. Heavy Analogues of Carboanions: Si–, Ge–, Sn– and Pb–Centered Anions
3.1 Introduction
3.2 Synthesis
3.3 Structure
3.4 Reactions and synthetic applications
3.5 Recent developments
3.6 Summary and outlook
References
4. Heavy Analogues of Carbenes: Silylenes, Germylenes, Stannylenes and Plumbylenes
4.1 Introduction
4.2 Generation
4.3 Spectroscopic identification
4.4 Structure
4.5 Reactions of transient species
4.6 Stable/persistent silylenes, germylenes, stannylenes, plumbylenes
4.7 Summary and outlook
References
5. Heavy Analogues of Alkenes, 1,3–dienes, Allenes, and Alkynes: Multiply Bonded Derivatives of Si, Ge, Sn and Pb
5.1 Introduction
5.2 Early studies: generation and identification
5.3 Stable derivatives (synthesis and structure)
5.4 Summary and outlook
References
6. Heavy Analogues of Aromatic Compounds
6.1 Introduction
6.2 Early studies
6.3 Stable compounds (synthesis and structure)6.4 Summary and outlook
References
Index


Okładka tylna:
Preface
Abbreviations
1. Heavy Analogues of Carbenium ions: Si–, Ge–, Sn– and Pb–Centered Cations
1.1 Introduction
1.2 Synthesis of RR’R’’E+ cations (E = Si–Pb)
1.3 Reactions and synthetic applications of RR’R’’E+ cations
1.4 Theoretical studies
1.5 Early studies of RR’R’’E+ cations: Free or Coordinated?
1.6 Stable RR’R’’E+ cations
1.7 Summary and outlook
References
2. Heavy Analogues of Organic Free Radicals: Si–, Ge–, Sn– and Pb–centered Radicals
2.1 Introduction
2.2 Early studies: transient species RR’R’’E•
2.3 Persistent radicals (generation and identification)
2.4 Stable radicals
2.5 Summary and outlook
References
3. Heavy Analogues of Carboanions: Si–, Ge–, Sn– and Pb–Centered Anions
3.1 Introduction
3.2 Synthesis
3.3 Structure
3.4 Reactions and synthetic applications
3.5 Recent developments
3.6 Summary and outlook
References
4. Heavy Analogues of Carbenes: Silylenes, Germylenes, Stannylenes and Plumbylenes
4.1 Introduction
4.2 Generation
4.3 Spectroscopic identification
4.4 Structure
4.5 Reactions of transient species
4.6 Stable/persistent silylenes, germylenes, stannylenes, plumbylenes
4.7 Summary and outlook
References
5. Heavy Analogues of Alkenes, 1,3–dienes, Allenes, and Alkynes: Multiply Bonded Derivatives of Si, Ge, Sn and Pb
5.1 Introduction
5.2 Early studies: generation and identification
5.3 Stable derivatives (synthesis and structure)
5.4 Summary and outlook
References
6. Heavy Analogues of Aromatic Compounds
6.1 Introduction
6.2 Early studies
6.3 Stable compounds (synthesis and structure)
6.4 Summary and outlook
References
Index