Efficient Methods for Preparing Silicon Compounds

Efficient Methods for Preparing Silicon Compounds is a unique and valuable handbook for chemists and students involved in advanced studies of preparative chemistry in academia and industry. Organized by the various coordination numbers (from two to six) of the central silicon atom of the reported compounds, this book provides researchers with a handy and immediate reference for any compound or properties needed in the area.

Edited by a renowned expert in the field, each chapter explores a different type of compound, thoroughly illustrated with useful schemes and supplemented by additional references. Knowledgeable contributors report on a broad range of compounds on which they have published and which are already used on a broad scale or have the potential to be used in the very near future to develop a new field of research or application in silicon chemistry.

Includes contributions and edits from leading experts in the fieldIncludes detailed chemical schemes and useful references for each preparative methodOrganized by the coordination numbers of the central silicon atom for each compound for easy navigationServes as a go-to primer for researchers in novel compositions of silicon matter

1. Preface 2. Preparation of the NHC (L1,2) and its Application for Synthesizing Lewis Base Stabilized Dichlorosilylene L1,2SiCl2 3. Lithium Tris(2,4,6-Triisopropylphenyl) Disilenide: A Versatile Reagent for the Transfer of the Disilenyl-Group 4. Preparation of a SiCS Three- and a SiO2C2 Five-Membered Ring System 5. Cobalt-Methylidyne-Silanetriol as Precursor for Catalytic Hydroformylation in a Two-Phase System 6. Convenient and High Yield Access to Silicon(II) Compounds Using Alkali Metal Amides as Dehydrochlorinating Agents 7. From Bis-silylene to Cyclodisiloxane 8. From bis-silylene to 1,4-disilabenzene: An Efficient Method to Generate Silicon Analogue of Benzene 9. Silanetriols: Synthesis, Characterization, and Structures 10. From Silanetriols to Aluminosilicates 11. Synthesis of a Zwitter-Ionic 2,4-Disila-1,3-Diphosphacyclobutadiene Compound 12. Facile Synthesis Of Silaimine Complex Phc(Ntbu)2si(Cl)=N(2,6-Ipr2c6h3) 13. One Pot Synthesis of E- [N(SiMe3)2](n1-Me5C5)Si=Si(n1-Me5C5)[N(SiMe3)2] 14. Access to Silicon(IV) Compounds with a Si-N Bond from Silicon(II) Precursors by N-H Bond Activation 15. Access to Silicon(IV) Compounds from Silicon(II) Precursors by C-H and C-F Bond Activation 16. Silylene as a Lewis Base with a Three-Coordinate Silicon 17. A Stable Silicon(II) Monohydride 18. Tetra(Silyl)Methane, (H3Si)4C, A Volatile Carbosilane for the Chemical Vapour Deposition of Amorphous Silicon Carbide Thin Films 19. Trimethylsilylperrhenate- A Non-Ionic Reagent Soluble in Organic Solvents for the Preparation of Perrhenates 20. (Monosodiumoxy)Organoalkoxysilanes (Rebrov Salts)- Polyfunctional Monomers For Silicone Syntheses 21. Hydrido Silyl Complexes of Chromium with Metal-Hydrogen-Silicon Three-Center Bonds